Hydrogen fuel cells are expected to be pivotal in the energetic transition towards renewable energy sources such as solar and wind power. However, their industrial scalability is severely hindered by the high cost and degradation rate of platinum catalysts, one of their key components. Addressing this…

Imagine we could convert the greenhouse gas CO2 into synthetic fuels using sustainable energy. This would enable us to reduce the amount of CO2 and at the same time store wind and solar energy in an innovative way. Chemist Akansha Goyal (Leiden University) is conducting fundamental research to make…

Single-layer graphene (SLG) has attracted considerable interest as a proton exchange membrane for direct methanol fuel cells (DMFCs), owing to its atomic thickness, mechanical robustness, and unique proton permeability.

The research described in this thesis focused on the preparation of S/N functionalized carbene ligands and their transition metal complexes, and the exploration of their application as electrocatalysts for proton reduction.

This thesis is a collection of experimental attempts to enhance photoluminescence of fluorescent molecules and quantum dots with single gold nanorods (GNRs) and relevant applications.

Promotor: M.T.M. Koper, Co-Promotor: L.B.F. Juurlink

In this dissertation, the synthesis and characterization of a series of iron complexes based on different ligand platforms are described.

In this thesis we have discussed several parameters that affect the electrochemical conversion of enviromentaly harmful molecules such as nitrates and carbon dioxide to more valuable and less deleterious compounds, in order to cast light onto the mechanism of the reaction to achieve an efficient and…

Promotor: M.T.M. Koper, Co-promotor: L. Juurlink

To design the ideal water oxidation catalyst, understanding of the catalytic mechanism and decomposition pathways is essential.

In eight chapters, the thesis of Rafaël Vos covers the effect of temperature and pressure on the electrochemical CO2 reduction.

The electrochemical oxygen reduction reaction (ORR) is an essential half-reaction for the utilization of hydrogen as a sustainable fuel, via the conversion of hydrogen to electrons and protons facilitated by the ORR. In the most common fuel cells, the ORR is requires high loadings of non-abundant platinum…

Carbon dioxide capture and utilization technologies are necessary to create a truly circular economy. The electrochemical reduction of carbon dioxide to formate is an appealing carbon utilization method as it can be performed at room temperature and pressure, it only requires two electrons, and it has…

In this dissertation iron-based homogeneous catalysts were synthesized, characterized and investigated for water oxidation activity.

Professor of Catalysis and Surface Chemistry Marc Koper has been appointed as member of the Koninklijke Nederlandse Akademie van Wetenschappen (KNAW). 'Very honourable, I see this as a confirmation of my work,’ says Koper.

Molecular complexes can be used as electrocatalysts for oxygen reduction, water oxidation, and/or hydrogen peroxide production.

This thesis advance our understanding and the application of molecular catalysts relevant to the reduction of oxygen as well as reduction of nitrite.

Green hydrogen is produced via a process called water electrolysis. During electrolysis water is split into oxygen and hydrogen.

Twenty years from now, the world population is estimated to be around 8.7 billion people, compared to the current 7.3 billion. In combination with the improvements in living standards and the corresponding growth in consumption, this will result in an enormous increase in the demand for food, consumables,…

The focus throughout this thesis will be on gathering fundamental studies of the detailed structure and composition of the electrode/electrolyte interface effect on the rate and mechanism of key electrocatalytic reactions.

During the 20th anniversary meeting of the Netherlands' Catalysis and Chemistry Conference, Marc Koper received the Netherlands Catalysis and Chemistry Award. ‘The ultimate candidate for the prize’, it says in one of the recommendation letters.

Through an NWO grant, chemist Rik Mom has received a tenure track position at the Leiden Institute of Chemistry, where he obtained his PhD cum laude in 2017. Mom will study the storage of sustainable energy by means of splitting water. Using new methods, he will investigate on an atomic scale which…

Chemist Prof. Marc Koper was awarded the Carl Wagner Memorial Award of the Electrochemical Society.

Bringing together chemists and physicists to thoroughly investigate how electrochemical processes work on the smallest scale. That is the goal of the new Advanced Nano-electrochemistry Institute of the Netherlands, or ANION for short. The consortium receives a Gravitation funding of 23.6 million euros…

On 1 August, Lars Jeuken started work as Professor of Biophysical Chemistry at the Leiden Institute of Chemistry (LIC). His research is at the intersection of biology and chemistry, but also involves physics and nanotechnology. Jeuken: ‘By linking nanoparticles to proteins and bacteria, we want to convert…

The E2CB programme has been launched to bring CO2 emissions to zero by 2050. The goal: to produce all raw materials for the chemical industry from sustainable sources. Professor of Electrochemistry Marc Koper is involved in the project.

Research of the Leiden Institute of Chemistry into the development of a sustainable fuel cell has accidentally resulted in an exceptionally efficient catalyst for the production of hydrogen peroxide. The catalyst, discovered by Dennis Hetterscheid and PhD candidate Michiel Langerman, may lead to a more…

A festive and honourable visit to our southern neighbours for professor Marc Koper. On Thursday 23 March, he received an honorary doctorate at the University of Antwerp. Koper gets the title in recognition of his expertise in the field of electrochemistry. ‘An important recognition for our research…

The electrochemical reduction of a group of organic compounds on platinum is strongly dependent on the arrangement of the atoms in the platinum surface. Christoph Bondue, postdoc in Marc Koper's group, published this in Nature Catalysis on 4 March. The reduction of such compounds is an important process…

It may well be possible to remove nitrate from polluted groundwater and at the same time produce ammonia in a sustainable way, according to PhD candidate Phebe van Langevelde and Professor Marc Koper of the Leiden Institute of Chemistry in Joule on 26 January. Together with a German colleague, they…

Both Leon Jacobse and Thom Hersbach from Marc Koper's research group obtained their PhDs cum laude. They both investigated changes on the surface of a platinum electrode. Jacobse studied this at a positive voltage, Hersbach at a negative voltage. Platinum has the potential to convert renewable energy…

Studying surfaces of solid materials: it may not seem relevant to energy consumption, but it is. Marcel Rost studies how platinum electrodes wear out. Those electrodes are a crucial component in the fuel cells of hydrogen-powered cars. ‘We need to make the switch from fossil fuel energy to hydrogen.…